Yeo, Chien Ing * and Tiekink, Edward R. T. * (2018) [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I). Molbank, 2018 (4). M1028. ISSN 1422-8599
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Abstract
The synthesis, spectroscopic characterization and X-ray crystal structure of the title compound, (4-tolyl)3PAu[SC(O-i-Pr)=NC6H4NO2-4] (1) are described. Spectroscopy exhibited the expected features confirming the formation of the compound. The molecular structure of 1 confirms the expected linear P–Au–S coordination geometry defined by thiolate-S and phosphane-P atoms. The nearly 7◦ deviation from linearity is ascribed to the close approach of the imine-bound phenyl group, indicative of a semi-localized Au . . . π(arene) interaction. The three-dimensional molecular packing is consolidated by methyl- and tolyl-C–H . . . O(nitro) and tolyl-C–H . . . π(tolyl) interactions.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | gold(I); thiocarbamate; Au . . . π interaction; X-ray crystallography |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Sunway University > School of Engineering and Technology [formerly School of Science and Technology until 2020] > Research Centre for Crystalline Materials moved to SMLS wef 2021 |
| Depositing User: | Dr Janaki Sinnasamy |
| Related URLs: | |
| Date Deposited: | 09 Nov 2018 02:18 |
| Last Modified: | 12 Oct 2020 07:49 |
| URI: | http://eprints.sunway.edu.my/id/eprint/933 |
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