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Tan, Yee Seng* and Yeo, Chien Ing* and Kwong, Huey Chong* and Tiekink, Edward R. T.* (2022) Unusual {⋯HNC2O⋯HCnO}, n = 1 or 2, synthons predominate in the molecular packing of one-dimensional coordination polymers, {Cd[S2P(OR)2]2(3LH2)}n, for R = Me and Et, but are precluded when R = i-Pr; 3LH2 = N,N′-bis(3-pyridylmethyl)oxalamide. CrystEngComm, 24 (16). pp. 2992-3004. ISSN 1466-8033