Ehsan, Muhammad Ali and Muhammad Mazhar, and Tiekink, Edward R. T. * (2016) Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II). IUCrData, 1 (1). x152429. ISSN 2414-3146
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Abstract
The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating dithiocarbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the molecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methylene-C-H...S interactions. These are connected into layers parallel to (10-2) via weak methyl-C-H...[pi](phenyl) interactions.
| Item Type: | Article |
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| Additional Information: | First author is with Center of Research Excellence in Nanotechnology (CENT), King Fahd University of Petrolium & Minerals; 2nd author is with Department of Chemistry, University of Malaya; 3rd author is with Centre for Crystalline Materials, Faculty of Science and Technology, Sunway University |
| Uncontrolled Keywords: | crystal structure; cadmium; dithiocarbamate |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Others > Non Sunway Academics Sunway University > School of Engineering and Technology [formerly School of Science and Technology until 2020] > Research Centre for Crystalline Materials moved to SMLS wef 2021 |
| Depositing User: | Ms. Molly Chuah |
| Related URLs: | |
| Date Deposited: | 02 Nov 2017 02:31 |
| Last Modified: | 07 Oct 2020 09:56 |
| URI: | http://eprints.sunway.edu.my/id/eprint/660 |
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