[O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I)

Yeo, Chien Ing * and Tiekink, Edward R. T. * (2018) [O-Isopropyl-N-(4-nitrophenyl)thiocarbamato-κS]-(tri-4-tolylphosphine-κP)gold(I). Molbank, 2018 (4). M1028. ISSN 1422-8599

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Official URL: http://doi.org/10.3390/M1028

Abstract

The synthesis, spectroscopic characterization and X-ray crystal structure of the title compound, (4-tolyl)3PAu[SC(O-i-Pr)=NC6H4NO2-4] (1) are described. Spectroscopy exhibited the expected features confirming the formation of the compound. The molecular structure of 1 confirms the expected linear P–Au–S coordination geometry defined by thiolate-S and phosphane-P atoms. The nearly 7◦ deviation from linearity is ascribed to the close approach of the imine-bound phenyl group, indicative of a semi-localized Au . . . π(arene) interaction. The three-dimensional molecular packing is consolidated by methyl- and tolyl-C–H . . . O(nitro) and tolyl-C–H . . . π(tolyl) interactions.

Item Type: Article
Uncontrolled Keywords: gold(I); thiocarbamate; Au . . . π interaction; X-ray crystallography
Subjects: Q Science > QD Chemistry
Divisions: Sunway University > School of Science and Technology > Research Centre for Crystalline Materials
Depositing User: Dr Janaki Sinnasamy
Related URLs:
Date Deposited: 09 Nov 2018 02:18
Last Modified: 22 Apr 2019 05:34
URI: http://eprints.sunway.edu.my/id/eprint/933

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