O-Methyl m-Tolylcarbamothioate

Yeo, Chien Ing * and Tiekink, Edward R. T. * (2018) O-Methyl m-Tolylcarbamothioate. Molbank, 2018 (3). M1020. ISSN 1422-8599

Tiekink O Methyl m Tolycarbamothioate.pdf

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Official URL: http://doi.org/10.3390/M1020


The synthesis, spectroscopic, and crystallographic characterisation of the title compound,O-methyl m-tolylcarbamothioate, MeOC(=S)N(H)(m-tolyl) (1), are described. The crystallographic study confirms the structure determined by spectroscopy and shows the presence of the thioamide tautomer, a syn-disposition of the thione-S and thioamide-N-H atoms and, in the crystal, thioamide-N-H . . . S(thione) hydrogen bonding leading to an eight-membered { . . . HNCS}2 synthon.

Item Type: Article
Uncontrolled Keywords: carbothioamide; thiocarbamate; X-ray crystallography; hydrogen bonding
Subjects: Q Science > QD Chemistry
Divisions: Sunway University > School of Science and Technology > Research Centre for Crystalline Materials
Depositing User: Dr Janaki Sinnasamy
Related URLs:
Date Deposited: 18 Sep 2018 08:51
Last Modified: 22 Apr 2019 05:48
URI: http://eprints.sunway.edu.my/id/eprint/902

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