Lee, See Mun * and Heard, Peter * and Tiekink, Edward R. T. * (2018) Molecular and supramolecular chemistry of mono- and di-selenium analogues of metal dithiocarbamates. Coordination Chemistry Reviews, 375. pp. 410-423. ISSN 0010-8545
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Abstract
This bibliographic review summarises the coordination chemistry of mono- and diselenium analogues of metal dithiocarbamate ligands, [RRꞌNCS2]-, as revealed by X-ray crystallography and spectroscopy (77Se NMR and infrared). The Se-ligands are usually chelating but, bridging modes, up to 4, are known. Reflecting the larger size, greater polarisability and presence of a polar-cap (-hole), selenium atoms are more likely to be involved in secondary-bonding (chalcogen-bonding) than sulphur when a competition exists. Isostructural relationships are established across the series in about one-third of the structures.
| Item Type: | Article |
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| Uncontrolled Keywords: | Selenothiocarbamate; Diselenocarbamate; Dithiocarbamate; Structures; Supramolecular chemistry; Secondary-bonding; 77Se NMR |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | General > Directorate Sunway University > School of Engineering and Technology [formerly School of Science and Technology until 2020] > Research Centre for Crystalline Materials moved to SMLS wef 2021 |
| Depositing User: | Dr Janaki Sinnasamy |
| Related URLs: | |
| Date Deposited: | 12 Sep 2018 07:09 |
| Last Modified: | 16 Apr 2021 03:56 |
| URI: | http://eprints.sunway.edu.my/id/eprint/898 |
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