Nazzatush Shimar Jamaludin, and Siti Nadiah Abdul Halim, and Tiekink, Edward R. T. * (2016) 3-(2-Hydroxyethyl)-3-methyl-1-(4-methylbenzoyl)thiourea. IUCrData, 1 (1). x152457. ISSN 2414-3146

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Official URL: http://dx.doi.org/10.1107/S2414314615024578


The title thio­urea derivative, C12H16N2O2S, has a twisted conformation with the dihedral angle between the NC(=S)N and O=CC6 planes being 35.45 (5)°. The observed conformation allows for an intra­molecular N-H...O hydrogen bond. In the mol­ecular packing, supra­molecular aggregation is based on hy­droxy-O-H...O(carbon­yl) hydrogen bonding and leads to supra­molecular helical chains along the a axis; chains are reinforced by N-methyl­ene-C-H...S and N-methyl-C-H...[pi](arene) inter­actions. Supra­molecular layers in the ab plane are formed as a result of tolyl-methyl-C-H...[pi](arene) inter­actions.

Item Type: Article
Additional Information: First and 2nd authors are with Department of Chemistry, University of Malaya; 3rd author is with Centre for Crystalline Materials, Faculty of Science and Technology, Sunway University
Uncontrolled Keywords: crystal structure; hydrogen bonding; thiourea
Subjects: Q Science > QD Chemistry
Divisions: Others > Non Sunway Academics
Sunway University > School of Engineering and Technology [formerly School of Science and Technology until 2020] > Research Centre for Crystalline Materials moved to SMLS wef 2021
Depositing User: Ms. Molly Chuah
Related URLs:
Date Deposited: 02 Nov 2017 03:25
Last Modified: 07 Oct 2020 09:54
URI: http://eprints.sunway.edu.my/id/eprint/663

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