Nazzatush Shimar Jamaludin, and Siti Nadiah Abdul Halim, and Tiekink, Edward R. T. * (2016) 3-(2-Hydroxyethyl)-3-methyl-1-(4-methylbenzoyl)thiourea. IUCrData, 1 (1). x152457. ISSN 2414-3146
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Abstract
The title thiourea derivative, C12H16N2O2S, has a twisted conformation with the dihedral angle between the NC(=S)N and O=CC6 planes being 35.45 (5)°. The observed conformation allows for an intramolecular N-H...O hydrogen bond. In the molecular packing, supramolecular aggregation is based on hydroxy-O-H...O(carbonyl) hydrogen bonding and leads to supramolecular helical chains along the a axis; chains are reinforced by N-methylene-C-H...S and N-methyl-C-H...[pi](arene) interactions. Supramolecular layers in the ab plane are formed as a result of tolyl-methyl-C-H...[pi](arene) interactions.
| Item Type: | Article |
|---|---|
| Additional Information: | First and 2nd authors are with Department of Chemistry, University of Malaya; 3rd author is with Centre for Crystalline Materials, Faculty of Science and Technology, Sunway University |
| Uncontrolled Keywords: | crystal structure; hydrogen bonding; thiourea |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Others > Non Sunway Academics Sunway University > School of Engineering and Technology [formerly School of Science and Technology until 2020] > Research Centre for Crystalline Materials moved to SMLS wef 2021 |
| Depositing User: | Ms. Molly Chuah |
| Related URLs: | |
| Date Deposited: | 02 Nov 2017 03:25 |
| Last Modified: | 07 Oct 2020 09:54 |
| URI: | http://eprints.sunway.edu.my/id/eprint/663 |
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