Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II)

Ehsan, Muhammad Ali and Muhammad Mazhar, and Tiekink, Edward R. T. * (2016) Bis(N-benzyl-N-methyldithiocarbamato-κ2S,S′)(pyridine-κN)cadmium(II). IUCrData, 1 (1). x152429. ISSN 2414-3146

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Official URL: http://dx.doi.org/10.1107/S2414314615024293

Abstract

The title compound, [Cd(C9H10NS2)2(C5H5N)], features a five-coordinate CdII atom, being coordinated by two nearly symmetrically chelating di­thio­carbamate ligands and a pyridine N atom. The resulting NS4 donor set defines a distorted coordination geometry tending toward square pyramidal. In the mol­ecular packing, centrosymmetric ten-membered {...HCNCS}2 synthons arise as a result of methyl­ene-C-H...S inter­actions. These are connected into layers parallel to (10-2) via weak methyl-C-H...[pi](phen­yl) inter­actions.

Item Type: Article
Additional Information: First author is with Center of Research Excellence in Nanotechnology (CENT), King Fahd University of Petrolium & Minerals; 2nd author is with Department of Chemistry, University of Malaya; 3rd author is with Centre for Crystalline Materials, Faculty of Science and Technology, Sunway University
Uncontrolled Keywords: crystal structure; cadmium; dithiocarbamate
Subjects: Q Science > QD Chemistry
Divisions: Others > Non Sunway Academics
Sunway University > School of Science and Technology > Research Centre for Crystalline Materials
Depositing User: Ms. Molly Chuah
Related URLs:
Date Deposited: 02 Nov 2017 02:31
Last Modified: 22 Apr 2019 06:27
URI: http://eprints.sunway.edu.my/id/eprint/660

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