[μ2-trans-1,2-Bis(pyridin-4-yl)ethene-κ2N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis

Jotani, Mukesh M. and Poplaukhin, Pavel and Arman, Hadi D. and Tiekink, Edward R. T. * (2016) [μ2-trans-1,2-Bis(pyridin-4-yl)ethene-κ2N:N′]bis{[1,2-bis(pyridin-4-yl)ethene-κN]bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]cadmium} acetonitrile tetrasolvate: crystal structure and Hirshfeld surface analysis. Acta Crystallographica Section E Crystallographic Communications, 72 (8). pp. 1085-1092. ISSN 2056-9890

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Official URL: http://dx.doi.org/10.1107/S2056989016010768

Abstract

The asymmetric unit of the title compound, [Cd2(C12H10N2)3(C6H12NOS2)4]·4C2H3N, comprises a CdII atom, two di­thio­carbamate (dtc) anions, one and a half trans-1,2-dipyridin-4-yl­ethyl­ene (bpe) mol­ecules and two aceto­nitrile solvent mol­ecules. The full binuclear complex is generated by the application of a centre of inversion. The dtc ligands are chelating, one bpe mol­ecule coordinates in a monodentate mode while the other is bidentate bridging. The resulting cis-N2S4 coordination geometry is based on an octa­hedron. Supra­molecular layers, sustained by hy­droxy-O—H⋯O(hy­droxy) and hy­droxy-O—H⋯N(bpe) hydrogen bonding, inter­penetrate to form a three-dimensional architecture; voids in this arrangement are occupied by the aceto­nitrile solvent mol­ecules. Additional inter­molecular inter­actions falling within the specified framework have been analysed by Hirshfeld surface analysis, including π–π inter­actions.

Item Type: Article
Additional Information: First author is with Department of Physics, Bhavan’s Sheth R. A. College of Science: 2nd author is with Chemical Abstracts Service; 3rd author is with Department of Chemistry, The University of Texas at San Antonio; 4th author is with Centre for Crystalline Materials, Faculty of Science and Technology, Sunway University
Uncontrolled Keywords: crystal structure; dithiocarbamate; 1,2-bis(pyridin-4-yl)ethene; interpenetration; hydrogen bonding; Hirshfeld surface analysis
Subjects: Q Science > QD Chemistry
Divisions: Others > Non Sunway Academics
Sunway University > School of Science and Technology > Research Centre for Crystalline Materials
Depositing User: Ms. Molly Chuah
Related URLs:
Date Deposited: 31 Oct 2017 05:56
Last Modified: 22 Apr 2019 06:24
URI: http://eprints.sunway.edu.my/id/eprint/648

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