An inorganic helix in the supramolecular structure of trimethyltin diphenylarsinate, [me3sn(o2asph2)]n: a structural comparison of triorganotin arsinates and phosphinates

Silaghi-Dumitrescu, Luminita and Harsan, Eugenia and Zukerman-Schpector, Julio and Tiekink, Edward R. T. * (2016) An inorganic helix in the supramolecular structure of trimethyltin diphenylarsinate, [me3sn(o2asph2)]n: a structural comparison of triorganotin arsinates and phosphinates. Revue Roumaine de Chimie, 61 (4-5). pp. 277-282. ISSN 0035-3930

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Abstract

The crystallographic structure analysis of [Me3Sn(O2AsPh2)]n reveals supramolecular association owing to symmetric bridges between Me3Sn centres afforded by O2AsPh2 groups. The resulting polymer has a helical topology. A systematic analysis of triorganotin arsinato and phosphinato analogues indicates a role for the remote substituents on aggregations patterns.

Item Type: Article
Additional Information: First and 5th authors are with Chemistry Department, Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University; 2nd author is with Horticulture Research Station, University of Agricultural Sciences and Veterinary Medicine, Roumania; 3rd author is with Laboratório de Cristalografia, Estereodinâmica e Modelagem Molecular, Departamento de Química, Universidade Federal de São Carlos; 4th author is with Centre for Crystalline Materials, Faculty of Science and Technology, Sunway University
Subjects: Q Science > QD Chemistry
Divisions: Others > Non Sunway Academics
Sunway University > School of Science and Technology > Research Centre for Crystalline Materials
Depositing User: Ms. Molly Chuah
Related URLs:
Date Deposited: 17 Oct 2017 07:55
Last Modified: 22 Apr 2019 06:33
URI: http://eprints.sunway.edu.my/id/eprint/599

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