Tiekink, Edward R. T. * (2023) Supramolecular Association via Hg···S Secondary-Bonding Interactions in Crystals of Organomercury(II) Species: A Survey of the Cambridge Structure Database. Crystals, 13 (3). p. 385. ISSN 2073-4352
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Abstract
The Cambridge Structural Database has been surveyed for crystals featuring organo-Hg···S secondary-bonding interactions within supramolecular aggregates. Nearly 50% of crystals where Hg···S interactions could potentially form, featured Hg···S contacts within zero- or one-dimensional supramolecular assemblies with only a few examples of two-dimensional arrays featuring Hg···S interactions. This high propensity of Hg···S contact formation reflects the inherent thiophilic nature of mercury but also the relatively open access to mercury owing to the linear C–Hg–S coordination geometries, the prevalence of close intramolecular Hg···S, Hg···O and Hg···N interactions notwithstanding.
| Item Type: | Article |
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| Uncontrolled Keywords: | Hg···S contacts; supramolecular chemistry; secondary-bonding; coordination polymers; crystal structures |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Sunway University > School of Medical and Life Sciences [formerly School of Healthcare and Medical Sciences until 2020] > Research Centre for Crystalline Materials |
| Depositing User: | Ms Yong Yee Chan |
| Related URLs: | |
| Date Deposited: | 27 Feb 2023 00:03 |
| Last Modified: | 27 Feb 2023 00:03 |
| URI: | http://eprints.sunway.edu.my/id/eprint/2142 |
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