Heard, Peter * and Tan, Yee Seng * and Yeo, Chien Ing * and Tiekink, Edward R. T. * (2021) The Coordination chemistry of imidomethanedithiolate di-anions: A structural comparison with their dithiocarbamate analogs. Inorganics, 9 (9). p. 71. ISSN 2304-6740
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Tiekink Coordination Chemistry inorganics 2021 9 71.pdf - Published Version Available under License Creative Commons Attribution Non-commercial No Derivatives. Download (3MB) | Preview |
Abstract
A review of the coordination chemistry along with the structural features of heavy element complexes of dithiocarbimate di-anions in the form of [(R)C=NCS2]2− for R = CN, alkyl, and aryl are described. This class of compound is far less studied compared with the well-explored dithiocarbamate mono-anions formulated as [R(R’)NCS2]− for R/R’ = H, alkyl, and aryl. The coordination chemistry of dithiocarbimate di-anions is dominated by a S,S-chelating mode; rare examples of alternative modes of coordination are evident. When comparisons are available, the structural motifs adopted by metal dithiocarbimate complexes match those found for their dithiocarbamate analogs, with only small, non-systematic variations in the M–S bond lengths
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | coordination chemistry; dithiocarbimate; metal imidomethane dithiolates; dithiocarbamate; structural comparison; synthesis; spectroscopy |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | General > Directorate Sunway University > School of Engineering and Technology [formerly School of Science and Technology until 2020] > Research Centre for Crystalline Materials moved to SMLS wef 2021 |
| Depositing User: | Dr Janaki Sinnasamy |
| Related URLs: | |
| Date Deposited: | 22 Sep 2021 09:00 |
| Last Modified: | 22 Sep 2021 09:00 |
| URI: | http://eprints.sunway.edu.my/id/eprint/1852 |
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