4-[(4-Chlorophenyl)carbamoyl]butanoic Acid

Hanifa, B. and Sirajuddin, M. and Bari, A and Lee, See Mun * and Lo, Kong Mun * and Tiekink, Edward R. T. * (2021) 4-[(4-Chlorophenyl)carbamoyl]butanoic Acid. Molbank, 2021 (2). M1209. ISSN 1422-8599

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Official URL: http://doi.org/10.3390/M1209


The X-ray crystal structure determination of the glutaric acid-amide derivative, 4-ClC6H4N(H)C(=O)(CH2)3C(=O)OH (1), is described. The backbone of the molecule adopts an extended, all-trans configuration but the terminal carboxylic acid and phenyl resides are twisted out of the plane through the bridging atoms, as seen in the torsion angles of O(carboxylic acid)–C(m)–C(m)–C(m) [13.9(5)°] and C(m)–N–C(p)–C(p) [47.1(4)°]; m = methylene and p = phenyl. The most striking feature of the molecular packing is the formation of supramolecular tapes mediated by carboxylic acid-O–H⋯O(carbonyl) and amide-N–H⋯O(amide) hydrogen bonding

Item Type: Article
Uncontrolled Keywords: glutaric acid amine; amide, carboxylic acid; hydrogen bending; x-ray crystallography
Subjects: Q Science > QD Chemistry
Divisions: Others > Non Sunway Academics
Sunway University > School of Medical and Life Sciences [formerly School of Healthcare and Medical Sciences until 2020] > Research Centre for Crystalline Materials
Depositing User: Dr Janaki Sinnasamy
Related URLs:
Date Deposited: 12 May 2021 06:42
Last Modified: 12 May 2021 06:42
URI: http://eprints.sunway.edu.my/id/eprint/1757

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