[Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol

Henderson, William and Okpareke, Obinna C. and Ainnul H. S. Azizan, * and Tiekink, Edward R. T. * (2019) [Dicyclohexyl(sulfanylidene)-λ5-phosphanyl]methanol. Molbank, 2019 (3). M1069. ISSN 1422-8599

[img]
Preview
Text
Tiekink Dicyclohexy .pdf - Published Version
Available under License Creative Commons Attribution Non-commercial.

Download (1MB) | Preview
Official URL: http://doi.org/10.3390/M1069

Abstract

The title compound, [dicyclohexyl(sulfanylidene)-λ5 -phosphanyl]methanol, Cy2P(=S)CH2OH (1), was obtained from the reaction between [Cy2P(CH2OH)2]Cl with one molar equivalent of NaOH and an excess of elemental sulfur (powdered). Characterization was by a single-crystal X-ray structure determination as well as IR, and 1D-NMR (1H,13C{1H}, 31P{1H}), and 2D-NMR (DEPT-135 and HSQC) spectroscopy, ESI mass spectrometry, and elemental analysis. X-ray crystallography on Compound 1 shows the phosphorus atom to be tetrahedrally coordinated within a non-symmetric C3S donor set but with relatively minor distortions from the ideal geometry. In the molecular packing, hydroxyl-O–H· · · S(thione) hydrogen bonds led to supramolecular helical chains along the b-axis direction.

Item Type: Article
Uncontrolled Keywords: phosphane sulfide; hydrogen bonding; ESI mass spectrometry; X-ray crystallograph
Subjects: Q Science > QD Chemistry
Divisions: Sunway University > School of Science and Technology > Research Centre for Crystalline Materials
Others > Non Sunway Academics
Depositing User: Dr Janaki Sinnasamy
Related URLs:
Date Deposited: 09 Jul 2019 08:00
Last Modified: 09 Jul 2019 08:00
URI: http://eprints.sunway.edu.my/id/eprint/1069

Actions (login required)

View Item View Item